Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Standard

Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur. / Du, Lin; Tang, Shanshan; Hansen, Anne Schou; Frandsen, Benjamin Normann; Maroun, Zeina; Kjærgaard, Henrik Grum.

I: Chemical Physics Letters, Bind 667, 2017, s. 146-153.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Du, L, Tang, S, Hansen, AS, Frandsen, BN, Maroun, Z & Kjærgaard, HG 2017, 'Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur', Chemical Physics Letters, bind 667, s. 146-153. https://doi.org/10.1016/j.cplett.2016.11.045

APA

Du, L., Tang, S., Hansen, A. S., Frandsen, B. N., Maroun, Z., & Kjærgaard, H. G. (2017). Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur. Chemical Physics Letters, 667, 146-153. https://doi.org/10.1016/j.cplett.2016.11.045

Vancouver

Du L, Tang S, Hansen AS, Frandsen BN, Maroun Z, Kjærgaard HG. Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur. Chemical Physics Letters. 2017;667:146-153. https://doi.org/10.1016/j.cplett.2016.11.045

Author

Du, Lin ; Tang, Shanshan ; Hansen, Anne Schou ; Frandsen, Benjamin Normann ; Maroun, Zeina ; Kjærgaard, Henrik Grum. / Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur. I: Chemical Physics Letters. 2017 ; Bind 667. s. 146-153.

Bibtex

@article{b91886b68fbb4d4baf4c737db5d3d161,
title = "Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur",
abstract = "The Osingle bondH⋯O and Osingle bondH⋯S hydrogen bonds were investigated by gas phase FTIR spectroscopy of alcohol–dimethylether and alcohol–dimethylsulfide complexes, with alcohols of increasing hydrogen bond donor strength; methanol (MeOH), ethanol (EtOH) and 2,2,2-trifluoroethanol (TFE). The TFE complexes are more stable and form stronger hydrogen bonds compared to complexes with MeOH and EtOH, which are comparable, and only for the stronger hydrogen bond donor (TFE) are the small differences in acceptor molecules highlighted. The equilibrium constant for complex formation was determined from the experimental and calculated intensity of the OH-stretching transition. The interactions are illustrated by theoretical calculations and topological analysis",
author = "Lin Du and Shanshan Tang and Hansen, {Anne Schou} and Frandsen, {Benjamin Normann} and Zeina Maroun and Kj{\ae}rgaard, {Henrik Grum}",
year = "2017",
doi = "10.1016/j.cplett.2016.11.045",
language = "English",
volume = "667",
pages = "146--153",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Subtle differences in the hydrogen bonding of alcohol to divalent oxygen and sulfur

AU - Du, Lin

AU - Tang, Shanshan

AU - Hansen, Anne Schou

AU - Frandsen, Benjamin Normann

AU - Maroun, Zeina

AU - Kjærgaard, Henrik Grum

PY - 2017

Y1 - 2017

N2 - The Osingle bondH⋯O and Osingle bondH⋯S hydrogen bonds were investigated by gas phase FTIR spectroscopy of alcohol–dimethylether and alcohol–dimethylsulfide complexes, with alcohols of increasing hydrogen bond donor strength; methanol (MeOH), ethanol (EtOH) and 2,2,2-trifluoroethanol (TFE). The TFE complexes are more stable and form stronger hydrogen bonds compared to complexes with MeOH and EtOH, which are comparable, and only for the stronger hydrogen bond donor (TFE) are the small differences in acceptor molecules highlighted. The equilibrium constant for complex formation was determined from the experimental and calculated intensity of the OH-stretching transition. The interactions are illustrated by theoretical calculations and topological analysis

AB - The Osingle bondH⋯O and Osingle bondH⋯S hydrogen bonds were investigated by gas phase FTIR spectroscopy of alcohol–dimethylether and alcohol–dimethylsulfide complexes, with alcohols of increasing hydrogen bond donor strength; methanol (MeOH), ethanol (EtOH) and 2,2,2-trifluoroethanol (TFE). The TFE complexes are more stable and form stronger hydrogen bonds compared to complexes with MeOH and EtOH, which are comparable, and only for the stronger hydrogen bond donor (TFE) are the small differences in acceptor molecules highlighted. The equilibrium constant for complex formation was determined from the experimental and calculated intensity of the OH-stretching transition. The interactions are illustrated by theoretical calculations and topological analysis

U2 - 10.1016/j.cplett.2016.11.045

DO - 10.1016/j.cplett.2016.11.045

M3 - Journal article

VL - 667

SP - 146

EP - 153

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

ER -

ID: 176370912