Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors

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Standard

Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors. / Christensen, J. B.; Bechgaard, K.; Johannsen, I.

I: Journal of Organic Chemistry, Bind 56, Nr. 25, 01.12.1991, s. 7055-7058.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Christensen, JB, Bechgaard, K & Johannsen, I 1991, 'Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors', Journal of Organic Chemistry, bind 56, nr. 25, s. 7055-7058. https://doi.org/10.1021/jo00025a020

APA

Christensen, J. B., Bechgaard, K., & Johannsen, I. (1991). Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors. Journal of Organic Chemistry, 56(25), 7055-7058. https://doi.org/10.1021/jo00025a020

Vancouver

Christensen JB, Bechgaard K, Johannsen I. Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors. Journal of Organic Chemistry. 1991 dec. 1;56(25):7055-7058. https://doi.org/10.1021/jo00025a020

Author

Christensen, J. B. ; Bechgaard, K. ; Johannsen, I. / Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors. I: Journal of Organic Chemistry. 1991 ; Bind 56, Nr. 25. s. 7055-7058.

Bibtex

@article{4fe20c6dbd944d1aac39b2775c70cf9a,
title = "Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors",
abstract = "The synthesis of substituted 1,6-dioxapyrenes, 2b-g, from 2,6-dipropyl-l,5-naphthalenediol (7a) or 2,6-dimethyl-1,5-naphthalenediol (7b) is described. Diol 7a was prepared by Claisen allylic rearrangement followed by reduction, and 7b was prepared by Mannich reaction of 1,5-naphthalenediol followed by base-promoted hydrogenolysis. The 1,6-dioxapyrenes can be oxidized to stable cation radicals at +0.2-0.35 V vs SCE and to dications at +0.8-1.20 V. The preparation of some tetracyanoquinodimethane salts and binary cation radical salts of the 1,6-dioxapyrenes is reported.",
author = "Christensen, {J. B.} and K. Bechgaard and I. Johannsen",
year = "1991",
month = dec,
day = "1",
doi = "10.1021/jo00025a020",
language = "English",
volume = "56",
pages = "7055--7058",
journal = "Journal of Organic Chemistry",
issn = "0022-3263",
publisher = "American Chemical Society",
number = "25",

}

RIS

TY - JOUR

T1 - Synthesis and Properties of Substituted 1,6-Dioxapyrene Donors

AU - Christensen, J. B.

AU - Bechgaard, K.

AU - Johannsen, I.

PY - 1991/12/1

Y1 - 1991/12/1

N2 - The synthesis of substituted 1,6-dioxapyrenes, 2b-g, from 2,6-dipropyl-l,5-naphthalenediol (7a) or 2,6-dimethyl-1,5-naphthalenediol (7b) is described. Diol 7a was prepared by Claisen allylic rearrangement followed by reduction, and 7b was prepared by Mannich reaction of 1,5-naphthalenediol followed by base-promoted hydrogenolysis. The 1,6-dioxapyrenes can be oxidized to stable cation radicals at +0.2-0.35 V vs SCE and to dications at +0.8-1.20 V. The preparation of some tetracyanoquinodimethane salts and binary cation radical salts of the 1,6-dioxapyrenes is reported.

AB - The synthesis of substituted 1,6-dioxapyrenes, 2b-g, from 2,6-dipropyl-l,5-naphthalenediol (7a) or 2,6-dimethyl-1,5-naphthalenediol (7b) is described. Diol 7a was prepared by Claisen allylic rearrangement followed by reduction, and 7b was prepared by Mannich reaction of 1,5-naphthalenediol followed by base-promoted hydrogenolysis. The 1,6-dioxapyrenes can be oxidized to stable cation radicals at +0.2-0.35 V vs SCE and to dications at +0.8-1.20 V. The preparation of some tetracyanoquinodimethane salts and binary cation radical salts of the 1,6-dioxapyrenes is reported.

UR - http://www.scopus.com/inward/record.url?scp=0039380734&partnerID=8YFLogxK

U2 - 10.1021/jo00025a020

DO - 10.1021/jo00025a020

M3 - Journal article

AN - SCOPUS:0039380734

VL - 56

SP - 7055

EP - 7058

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 25

ER -

ID: 261047067