Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex

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Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex. / Schau-Magnussen, Magnus; Malcho, Phillip; Herbst, Konrad; Brorson, Michael; Bendix, Jesper.

I: Dalton Transactions (Print Edition), Bind 40, Nr. 16, 28.04.2011, s. 4212-6.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Schau-Magnussen, M, Malcho, P, Herbst, K, Brorson, M & Bendix, J 2011, 'Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex', Dalton Transactions (Print Edition), bind 40, nr. 16, s. 4212-6. https://doi.org/10.1039/c0dt01791d

APA

Schau-Magnussen, M., Malcho, P., Herbst, K., Brorson, M., & Bendix, J. (2011). Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex. Dalton Transactions (Print Edition), 40(16), 4212-6. https://doi.org/10.1039/c0dt01791d

Vancouver

Schau-Magnussen M, Malcho P, Herbst K, Brorson M, Bendix J. Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex. Dalton Transactions (Print Edition). 2011 apr. 28;40(16):4212-6. https://doi.org/10.1039/c0dt01791d

Author

Schau-Magnussen, Magnus ; Malcho, Phillip ; Herbst, Konrad ; Brorson, Michael ; Bendix, Jesper. / Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex. I: Dalton Transactions (Print Edition). 2011 ; Bind 40, Nr. 16. s. 4212-6.

Bibtex

@article{7fafff91080b4c1387db59b9f2b6cebd,
title = "Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex",
abstract = "Reaction of the organometallic aqua ion [Cp*Ir(H(2)O)(3)](2+) with tert-butyl(trimethylsilyl)amine in acetone yielded a novel trinuclear (µ(3)-oxido)(µ(3)-imido)pentamethylcyclopentadienyliridium(iii) complex, [(Cp*Ir)(3)(O)(N(t)Bu)](2+). Single crystal structure analyses show the complex can be isolated both in the double salt ((t)BuNH(3))[(Cp*Ir)(3)(O)(N(t)Bu)](CF(3)SO(3))(3) (1) and in the simple triflate [(Cp*Ir)(3)(O)(N(t)Bu)](CF(3)SO(3))(2) (2). The double salt is stabilized by hydrogen bonding between the tert-butylammonium ion and the three triflate anions. It is the first time that a trinuclear (µ(3)-oxido)(µ(3)-imido) transition metal complex has been structurally characterized.",
author = "Magnus Schau-Magnussen and Phillip Malcho and Konrad Herbst and Michael Brorson and Jesper Bendix",
year = "2011",
month = apr,
day = "28",
doi = "10.1039/c0dt01791d",
language = "English",
volume = "40",
pages = "4212--6",
journal = "Acta chemica Scandinavica. Series A: Physical and inorganic chemistry",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "16",

}

RIS

TY - JOUR

T1 - Synthesis and X-ray crystal structure of a novel organometallic (µ(3)-oxido)(µ(3)-imido) trinuclear iridium complex

AU - Schau-Magnussen, Magnus

AU - Malcho, Phillip

AU - Herbst, Konrad

AU - Brorson, Michael

AU - Bendix, Jesper

PY - 2011/4/28

Y1 - 2011/4/28

N2 - Reaction of the organometallic aqua ion [Cp*Ir(H(2)O)(3)](2+) with tert-butyl(trimethylsilyl)amine in acetone yielded a novel trinuclear (µ(3)-oxido)(µ(3)-imido)pentamethylcyclopentadienyliridium(iii) complex, [(Cp*Ir)(3)(O)(N(t)Bu)](2+). Single crystal structure analyses show the complex can be isolated both in the double salt ((t)BuNH(3))[(Cp*Ir)(3)(O)(N(t)Bu)](CF(3)SO(3))(3) (1) and in the simple triflate [(Cp*Ir)(3)(O)(N(t)Bu)](CF(3)SO(3))(2) (2). The double salt is stabilized by hydrogen bonding between the tert-butylammonium ion and the three triflate anions. It is the first time that a trinuclear (µ(3)-oxido)(µ(3)-imido) transition metal complex has been structurally characterized.

AB - Reaction of the organometallic aqua ion [Cp*Ir(H(2)O)(3)](2+) with tert-butyl(trimethylsilyl)amine in acetone yielded a novel trinuclear (µ(3)-oxido)(µ(3)-imido)pentamethylcyclopentadienyliridium(iii) complex, [(Cp*Ir)(3)(O)(N(t)Bu)](2+). Single crystal structure analyses show the complex can be isolated both in the double salt ((t)BuNH(3))[(Cp*Ir)(3)(O)(N(t)Bu)](CF(3)SO(3))(3) (1) and in the simple triflate [(Cp*Ir)(3)(O)(N(t)Bu)](CF(3)SO(3))(2) (2). The double salt is stabilized by hydrogen bonding between the tert-butylammonium ion and the three triflate anions. It is the first time that a trinuclear (µ(3)-oxido)(µ(3)-imido) transition metal complex has been structurally characterized.

U2 - 10.1039/c0dt01791d

DO - 10.1039/c0dt01791d

M3 - Journal article

C2 - 21387064

VL - 40

SP - 4212

EP - 4216

JO - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

JF - Acta chemica Scandinavica. Series A: Physical and inorganic chemistry

SN - 1477-9226

IS - 16

ER -

ID: 33240934