Templation and Concentration Drive Conversion between a FeII12L12Pseudoicosahedron, a FeII4L4Tetrahedron, and a FeII2L3Helicate
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Templation and Concentration Drive Conversion between a FeII12L12Pseudoicosahedron, a FeII4L4Tetrahedron, and a FeII2L3Helicate. / Zhang, Dawei; Gan, Quan; Plajer, Alex J.; Lavendomme, Roy; Ronson, Tanya K.; Lu, Zifei; Jensen, Jesper D.; Laursen, Bo W.; Nitschke, Jonathan R.
I: Journal of the American Chemical Society, Bind 144, 2022, s. 1106-1112.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Templation and Concentration Drive Conversion between a FeII12L12Pseudoicosahedron, a FeII4L4Tetrahedron, and a FeII2L3Helicate
AU - Zhang, Dawei
AU - Gan, Quan
AU - Plajer, Alex J.
AU - Lavendomme, Roy
AU - Ronson, Tanya K.
AU - Lu, Zifei
AU - Jensen, Jesper D.
AU - Laursen, Bo W.
AU - Nitschke, Jonathan R.
N1 - Publisher Copyright: ©
PY - 2022
Y1 - 2022
N2 - We report the construction of three structurally distinct self-assembled architectures: FeII12L12 pseudoicosahedron 1, FeII2L3 helicate 2, and FeII4L4 tetrahedron 3, formed from a single triazatriangulenium subcomponent A under different reaction conditions. Pseudoicosahedral capsule 1 is the largest formed through subcomponent self-assembly to date, with an outer-sphere diameter of 5.4 nm and a cavity volume of 15 nm3. The outcome of self-assembly depended upon concentration, where the formation of pseudoicosahedron 1 was favored at higher concentrations, while helicate 2 exclusively formed at lower concentrations. The conversion of pseudoicosahedron 1 or helicate 2 into tetrahedron 3 occurred following the addition of a CB11H12- or B12F122- template.
AB - We report the construction of three structurally distinct self-assembled architectures: FeII12L12 pseudoicosahedron 1, FeII2L3 helicate 2, and FeII4L4 tetrahedron 3, formed from a single triazatriangulenium subcomponent A under different reaction conditions. Pseudoicosahedral capsule 1 is the largest formed through subcomponent self-assembly to date, with an outer-sphere diameter of 5.4 nm and a cavity volume of 15 nm3. The outcome of self-assembly depended upon concentration, where the formation of pseudoicosahedron 1 was favored at higher concentrations, while helicate 2 exclusively formed at lower concentrations. The conversion of pseudoicosahedron 1 or helicate 2 into tetrahedron 3 occurred following the addition of a CB11H12- or B12F122- template.
U2 - 10.1021/jacs.1c11536
DO - 10.1021/jacs.1c11536
M3 - Journal article
C2 - 35014803
AN - SCOPUS:85123873914
VL - 144
SP - 1106
EP - 1112
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
ER -
ID: 291538256