The coordination chemistry of p-tert-butylcalix[4]arene with paramagnetic transition and lanthanide metal ions: an Edinburgh Perspective
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The coordination chemistry of p-tert-butylcalix[4]arene with paramagnetic transition and lanthanide metal ions : an Edinburgh Perspective. / Wilson, Lucinda R. B.; Coletta, Marco; Evangelisiti, Marco; Piligkos, Stergios; Dalgarno, Scott J.; Brechin, Euan K.
I: Journal of the Chemical Society. Dalton Transactions, Bind 51, Nr. 11, 2022, s. 4213–4226.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - The coordination chemistry of p-tert-butylcalix[4]arene with paramagnetic transition and lanthanide metal ions
T2 - an Edinburgh Perspective
AU - Wilson, Lucinda R. B.
AU - Coletta, Marco
AU - Evangelisiti, Marco
AU - Piligkos, Stergios
AU - Dalgarno, Scott J.
AU - Brechin, Euan K.
N1 - Correction: https://doi.org/10.1039/D2DT90040H
PY - 2022
Y1 - 2022
N2 - The calix[4]arene scaffold is an extremely versatile supramolecular platform that has found widespread use across many research areas due to its synthetic versatility, controllable conformation, and the presence of cavities or clefts for tailorable guest binding. The tetraphenolic lower-rim of p-tert-butylcalix[4]arene in the cone conformation is ideal for binding a variety of paramagnetic transition and lanthanide metals, and in this Perspective we review our endeavours in using such complexes as metalloligands in the synthesis of polymetallic clusters that have fascinating structural and magnetic properties. By varying reactants, stoichiometries and reaction or crystallisation conditions it is possible to access an incredible range of clusters, all of which show consistent trends in coordination preferences and assembly behaviours. p-tert-Butylcalix[4]arene has already given so much, yet it is likely that this remarkable parent calixarene will continue to surprise chemists and deliver even more in terms of novelty and function.
AB - The calix[4]arene scaffold is an extremely versatile supramolecular platform that has found widespread use across many research areas due to its synthetic versatility, controllable conformation, and the presence of cavities or clefts for tailorable guest binding. The tetraphenolic lower-rim of p-tert-butylcalix[4]arene in the cone conformation is ideal for binding a variety of paramagnetic transition and lanthanide metals, and in this Perspective we review our endeavours in using such complexes as metalloligands in the synthesis of polymetallic clusters that have fascinating structural and magnetic properties. By varying reactants, stoichiometries and reaction or crystallisation conditions it is possible to access an incredible range of clusters, all of which show consistent trends in coordination preferences and assembly behaviours. p-tert-Butylcalix[4]arene has already given so much, yet it is likely that this remarkable parent calixarene will continue to surprise chemists and deliver even more in terms of novelty and function.
U2 - 10.1039/D2DT00152G
DO - 10.1039/D2DT00152G
M3 - Journal article
VL - 51
SP - 4213
EP - 4226
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
SN - 1472-7773
IS - 11
ER -
ID: 298377830