The effect of inosine on the spectroscopic properties and crystal structure of a NIR-emitting DNA-stabilized silver nanocluster
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The effect of replacing guanosines with inosines in the two stabilizing strands (5 '-CACCTAGCGA-3 ') of the NIR emissive DNA-Ag16NC was investigated. The spectroscopic behavior of the inosine mutants is position-dependent: when the guanosine in position 7 was exchanged, the nanosecond fluorescence decay time shortened, while having the inosine in position 9 made the decay time longer. Thanks to structural information gained from single crystal X-ray diffraction measurements, it was possible to propose a mechanistic origin for the observed changes.
Originalsprog | Engelsk |
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Tidsskrift | Nanoscale Advances |
Vol/bind | 4 |
Udgave nummer | 15 |
Sider (fra-til) | 3212–3217 |
Antal sider | 6 |
ISSN | 2516-0230 |
DOI | |
Status | Udgivet - 20 jun. 2022 |
ID: 313051858