The mixed-valent (μ-nitrido)-dimanganese complex anion [(CN)5Mn(v)(μ- N)Mn(II)(CN)5]6-
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The mixed-valent (μ-nitrido)-dimanganese complex anion [(CN)5Mn(v)(μ- N)Mn(II)(CN)5]6-. / Bendix, Jesper; Weyhermüller, Thomas; Bill, Eckhard; Wieghardt, Karl.
I: Angewandte Chemie - International Edition, Bind 38, Nr. 18, 17.09.1999, s. 2766-2768.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - The mixed-valent (μ-nitrido)-dimanganese complex anion [(CN)5Mn(v)(μ- N)Mn(II)(CN)5]6-
AU - Bendix, Jesper
AU - Weyhermüller, Thomas
AU - Bill, Eckhard
AU - Wieghardt, Karl
PY - 1999/9/17
Y1 - 1999/9/17
N2 - Localized valencies are displayed by the Mn(v)Mn(II) complex ion 1. This is the key finding from X-ray structure analysis, as well as vibrational and EPR spectroscopic investigations on 1 obtained by the reaction of manganese(II) and [Mn(v)(N)(CN)5]3- salts in aqueous 1M NaCN solution. Remarkably, the asymmetry is induced by the nitrogen atom bridge.
AB - Localized valencies are displayed by the Mn(v)Mn(II) complex ion 1. This is the key finding from X-ray structure analysis, as well as vibrational and EPR spectroscopic investigations on 1 obtained by the reaction of manganese(II) and [Mn(v)(N)(CN)5]3- salts in aqueous 1M NaCN solution. Remarkably, the asymmetry is induced by the nitrogen atom bridge.
KW - Manganese
KW - Mixed-valent compounds
KW - Multiple bonds
KW - Nitrides
UR - http://www.scopus.com/inward/record.url?scp=0344132636&partnerID=8YFLogxK
M3 - Journal article
AN - SCOPUS:0344132636
VL - 38
SP - 2766
EP - 2768
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
SN - 1433-7851
IS - 18
ER -
ID: 240004097