The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study

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Standard

The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study. / Lund Thomsen, E.; Nielsen, Ole J.; Egsgaard, Helge.

I: Chemical Physics Letters, Bind 215, Nr. 1-3, 26.11.1993, s. 257-263.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Lund Thomsen, E, Nielsen, OJ & Egsgaard, H 1993, 'The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study', Chemical Physics Letters, bind 215, nr. 1-3, s. 257-263. https://doi.org/10.1016/0009-2614(93)89297-U

APA

Lund Thomsen, E., Nielsen, O. J., & Egsgaard, H. (1993). The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study. Chemical Physics Letters, 215(1-3), 257-263. https://doi.org/10.1016/0009-2614(93)89297-U

Vancouver

Lund Thomsen E, Nielsen OJ, Egsgaard H. The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study. Chemical Physics Letters. 1993 nov. 26;215(1-3):257-263. https://doi.org/10.1016/0009-2614(93)89297-U

Author

Lund Thomsen, E. ; Nielsen, Ole J. ; Egsgaard, Helge. / The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study. I: Chemical Physics Letters. 1993 ; Bind 215, Nr. 1-3. s. 257-263.

Bibtex

@article{8981b0a57ad04db4b1a0aa058a8507d4,
title = "The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study",
abstract = "The mechanism of the reaction between H and CH3NO2, has been studied in a discharge flow system using electron paramagnetic resonance and modulated molecular beam mass spectrometry for the detection of reactants and products. Deuterium atoms have, in addition to CD3NO2, been used to support the proposed reaction mechanism. The reaction was studied with the atomic reactant in slight excess at 298 K and a total pressure of 2 Torr. Two concurrent reaction channels: (1a) H+CH3NO2→HONO+{radical dot}CH3 and (1b) H+CH3NO2→CH3NO+{radical dot}OH were observed. The branching ratio, k1a/(k1a+k1b), is 0.7±0.2.",
author = "{Lund Thomsen}, E. and Nielsen, {Ole J.} and Helge Egsgaard",
year = "1993",
month = nov,
day = "26",
doi = "10.1016/0009-2614(93)89297-U",
language = "English",
volume = "215",
pages = "257--263",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - The reaction of nitromethane with hydrogen and deuterium atoms in the gas phase. A mechanistic study

AU - Lund Thomsen, E.

AU - Nielsen, Ole J.

AU - Egsgaard, Helge

PY - 1993/11/26

Y1 - 1993/11/26

N2 - The mechanism of the reaction between H and CH3NO2, has been studied in a discharge flow system using electron paramagnetic resonance and modulated molecular beam mass spectrometry for the detection of reactants and products. Deuterium atoms have, in addition to CD3NO2, been used to support the proposed reaction mechanism. The reaction was studied with the atomic reactant in slight excess at 298 K and a total pressure of 2 Torr. Two concurrent reaction channels: (1a) H+CH3NO2→HONO+{radical dot}CH3 and (1b) H+CH3NO2→CH3NO+{radical dot}OH were observed. The branching ratio, k1a/(k1a+k1b), is 0.7±0.2.

AB - The mechanism of the reaction between H and CH3NO2, has been studied in a discharge flow system using electron paramagnetic resonance and modulated molecular beam mass spectrometry for the detection of reactants and products. Deuterium atoms have, in addition to CD3NO2, been used to support the proposed reaction mechanism. The reaction was studied with the atomic reactant in slight excess at 298 K and a total pressure of 2 Torr. Two concurrent reaction channels: (1a) H+CH3NO2→HONO+{radical dot}CH3 and (1b) H+CH3NO2→CH3NO+{radical dot}OH were observed. The branching ratio, k1a/(k1a+k1b), is 0.7±0.2.

UR - http://www.scopus.com/inward/record.url?scp=43949169182&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(93)89297-U

DO - 10.1016/0009-2614(93)89297-U

M3 - Journal article

AN - SCOPUS:43949169182

VL - 215

SP - 257

EP - 263

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-3

ER -

ID: 228194846