The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI)

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Standard

The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI). / Magnussen, Magnus; Bendix, Jesper.

I: Acta Crystallographica. Section C: Crystal Structure Communications, Bind 59, Nr. Pt 9, 01.09.2003, s. m342-4.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Magnussen, M & Bendix, J 2003, 'The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI)', Acta Crystallographica. Section C: Crystal Structure Communications, bind 59, nr. Pt 9, s. m342-4.

APA

Magnussen, M., & Bendix, J. (2003). The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI). Acta Crystallographica. Section C: Crystal Structure Communications, 59(Pt 9), m342-4.

Vancouver

Magnussen M, Bendix J. The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI). Acta Crystallographica. Section C: Crystal Structure Communications. 2003 sep. 1;59(Pt 9):m342-4.

Author

Magnussen, Magnus ; Bendix, Jesper. / The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI). I: Acta Crystallographica. Section C: Crystal Structure Communications. 2003 ; Bind 59, Nr. Pt 9. s. m342-4.

Bibtex

@article{09b1deece3bb4285ae79aa8f9d3f7ec8,
title = "The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI)",
abstract = "The title compound, mer-[RuCl(3)N(C(18)H(15)As)(2)], is the first structurally characterized example of a nitride complex in which ruthenium is six-coordinated to monodentate ligands only. The Ru[triple-bond]N bond length [1.6161 (15) A] is relatively long, and the trans influence of the nitride ligand is reflected by the difference between the Ru--Cl(trans) and Ru--Cl(cis) bond lengths [0.1234 (4) A]. The N--Ru--Cl(trans) axis is sited on a twofold axis.",
author = "Magnus Magnussen and Jesper Bendix",
year = "2003",
month = sep,
day = "1",
language = "English",
volume = "59",
pages = "m342--4",
journal = "Acta crystallographica. Section C, Structural chemistry",
issn = "2053-2296",
publisher = "Wiley",
number = "Pt 9",

}

RIS

TY - JOUR

T1 - The trans influence in mer-trichloronitridobis(triphenylarsine)ruthenium(VI)

AU - Magnussen, Magnus

AU - Bendix, Jesper

PY - 2003/9/1

Y1 - 2003/9/1

N2 - The title compound, mer-[RuCl(3)N(C(18)H(15)As)(2)], is the first structurally characterized example of a nitride complex in which ruthenium is six-coordinated to monodentate ligands only. The Ru[triple-bond]N bond length [1.6161 (15) A] is relatively long, and the trans influence of the nitride ligand is reflected by the difference between the Ru--Cl(trans) and Ru--Cl(cis) bond lengths [0.1234 (4) A]. The N--Ru--Cl(trans) axis is sited on a twofold axis.

AB - The title compound, mer-[RuCl(3)N(C(18)H(15)As)(2)], is the first structurally characterized example of a nitride complex in which ruthenium is six-coordinated to monodentate ligands only. The Ru[triple-bond]N bond length [1.6161 (15) A] is relatively long, and the trans influence of the nitride ligand is reflected by the difference between the Ru--Cl(trans) and Ru--Cl(cis) bond lengths [0.1234 (4) A]. The N--Ru--Cl(trans) axis is sited on a twofold axis.

M3 - Journal article

C2 - 12944639

VL - 59

SP - m342-4

JO - Acta crystallographica. Section C, Structural chemistry

JF - Acta crystallographica. Section C, Structural chemistry

SN - 2053-2296

IS - Pt 9

ER -

ID: 33326253