Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

Standard

Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors. / Feng, Linlin; Dong, Huanli; Li, Qingyuan; Zhu, Weigang; Qiu, Gege; Ding, Shang; Li, Yang; Christensen, Mikkel Andreas; Parker, Christian Richard; Wei, Zhongming; Nielsen, Mogens Brøndsted; Hu, Wenping.

I: Science China Materials, Bind 60, Nr. 1, 2017, s. 75-82.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

Harvard

Feng, L, Dong, H, Li, Q, Zhu, W, Qiu, G, Ding, S, Li, Y, Christensen, MA, Parker, CR, Wei, Z, Nielsen, MB & Hu, W 2017, 'Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors', Science China Materials, bind 60, nr. 1, s. 75-82. https://doi.org/10.1007/s40843-016-5137-4

APA

Feng, L., Dong, H., Li, Q., Zhu, W., Qiu, G., Ding, S., Li, Y., Christensen, M. A., Parker, C. R., Wei, Z., Nielsen, M. B., & Hu, W. (2017). Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors. Science China Materials, 60(1), 75-82. https://doi.org/10.1007/s40843-016-5137-4

Vancouver

Feng L, Dong H, Li Q, Zhu W, Qiu G, Ding S o.a. Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors. Science China Materials. 2017;60(1):75-82. https://doi.org/10.1007/s40843-016-5137-4

Author

Feng, Linlin ; Dong, Huanli ; Li, Qingyuan ; Zhu, Weigang ; Qiu, Gege ; Ding, Shang ; Li, Yang ; Christensen, Mikkel Andreas ; Parker, Christian Richard ; Wei, Zhongming ; Nielsen, Mogens Brøndsted ; Hu, Wenping. / Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors. I: Science China Materials. 2017 ; Bind 60, Nr. 1. s. 75-82.

Bibtex

@article{b002d25591bd4563a5a7af93ac5395d2,
title = "Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors",
abstract = "It is a common phenomenon for organic semiconductors to crystallize in two or more polymorphs, leading to various molecular packings and different charge transport properties. Therefore, it is a crucial issue of tuning molecular crystal polymorphs (i.e., adjusting the same molecule with different packing arrangements in solid state) towards efficient charge transport and high performance devices. Here, the choice of solvent had a marked effect on controlling the growth of α-phase ribbon and β-phase platelet during crystallization for an indenofluorene (IF) π-extended tetrathiafulvalene (TTF)-based cruciform molecule, named as IF-TTF. The charge carrier mobility of the α-phase IF-TTF crystals was more than one order of magnitude higher than that of β-phase crystals, suggesting the importance of reasonably tuning molecular packing in solid state for the improvement of charge transport in organic semiconductors",
keywords = "organic semiconductor, crystal polymorphs, tetrathiafulvalene-based cruciform molecule, field-effect transistor, charge carrier mobility",
author = "Linlin Feng and Huanli Dong and Qingyuan Li and Weigang Zhu and Gege Qiu and Shang Ding and Yang Li and Christensen, {Mikkel Andreas} and Parker, {Christian Richard} and Zhongming Wei and Nielsen, {Mogens Br{\o}ndsted} and Wenping Hu",
year = "2017",
doi = "10.1007/s40843-016-5137-4",
language = "English",
volume = "60",
pages = "75--82",
journal = "Science China Materials",
issn = "2095-8226",
publisher = "Zhongguo Kexue Zazhishe",
number = "1",

}

RIS

TY - JOUR

T1 - Tuning crystal polymorphs of a Π-extended tetrathiafulvalene-based cruciform molecule towards high-performance organic field-effect transistors

AU - Feng, Linlin

AU - Dong, Huanli

AU - Li, Qingyuan

AU - Zhu, Weigang

AU - Qiu, Gege

AU - Ding, Shang

AU - Li, Yang

AU - Christensen, Mikkel Andreas

AU - Parker, Christian Richard

AU - Wei, Zhongming

AU - Nielsen, Mogens Brøndsted

AU - Hu, Wenping

PY - 2017

Y1 - 2017

N2 - It is a common phenomenon for organic semiconductors to crystallize in two or more polymorphs, leading to various molecular packings and different charge transport properties. Therefore, it is a crucial issue of tuning molecular crystal polymorphs (i.e., adjusting the same molecule with different packing arrangements in solid state) towards efficient charge transport and high performance devices. Here, the choice of solvent had a marked effect on controlling the growth of α-phase ribbon and β-phase platelet during crystallization for an indenofluorene (IF) π-extended tetrathiafulvalene (TTF)-based cruciform molecule, named as IF-TTF. The charge carrier mobility of the α-phase IF-TTF crystals was more than one order of magnitude higher than that of β-phase crystals, suggesting the importance of reasonably tuning molecular packing in solid state for the improvement of charge transport in organic semiconductors

AB - It is a common phenomenon for organic semiconductors to crystallize in two or more polymorphs, leading to various molecular packings and different charge transport properties. Therefore, it is a crucial issue of tuning molecular crystal polymorphs (i.e., adjusting the same molecule with different packing arrangements in solid state) towards efficient charge transport and high performance devices. Here, the choice of solvent had a marked effect on controlling the growth of α-phase ribbon and β-phase platelet during crystallization for an indenofluorene (IF) π-extended tetrathiafulvalene (TTF)-based cruciform molecule, named as IF-TTF. The charge carrier mobility of the α-phase IF-TTF crystals was more than one order of magnitude higher than that of β-phase crystals, suggesting the importance of reasonably tuning molecular packing in solid state for the improvement of charge transport in organic semiconductors

KW - organic semiconductor

KW - crystal polymorphs

KW - tetrathiafulvalene-based cruciform molecule

KW - field-effect transistor

KW - charge carrier mobility

U2 - 10.1007/s40843-016-5137-4

DO - 10.1007/s40843-016-5137-4

M3 - Journal article

VL - 60

SP - 75

EP - 82

JO - Science China Materials

JF - Science China Materials

SN - 2095-8226

IS - 1

ER -

ID: 176371547