Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals

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Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals. / Anastasi, Christopher; Broomfield, Mark; Nielsen, Ole John; Pagsberg, Palle.

I: Chemical Physics Letters, Bind 182, Nr. 6, 16.08.1991, s. 643-648.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Anastasi, C, Broomfield, M, Nielsen, OJ & Pagsberg, P 1991, 'Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals', Chemical Physics Letters, bind 182, nr. 6, s. 643-648. https://doi.org/10.1016/0009-2614(91)90139-Z

APA

Anastasi, C., Broomfield, M., Nielsen, O. J., & Pagsberg, P. (1991). Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals. Chemical Physics Letters, 182(6), 643-648. https://doi.org/10.1016/0009-2614(91)90139-Z

Vancouver

Anastasi C, Broomfield M, Nielsen OJ, Pagsberg P. Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals. Chemical Physics Letters. 1991 aug. 16;182(6):643-648. https://doi.org/10.1016/0009-2614(91)90139-Z

Author

Anastasi, Christopher ; Broomfield, Mark ; Nielsen, Ole John ; Pagsberg, Palle. / Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals. I: Chemical Physics Letters. 1991 ; Bind 182, Nr. 6. s. 643-648.

Bibtex

@article{ce3f8fdab60a46a89fea36db6327a599,
title = "Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals",
abstract = "The ultraviolet absorption spectra of CH3S and CH2SH radicals have been measured between 215 and 380 nm using the pulse-radiolysis/kinetic-abso method. One absorption band between 250 and 300 nm and one around 215 nm have been tentatively assigned to the CH2SH and CH3S radicals, respectively. This spectrum has been used to measure the self-reaction rates of these radicals. Rate constants of 4 × 10-11 and 7 × 10-11 cm3 molecule-1 s-1 have been measured at 298 K for CH3S and CH2SH recombination, respectively. The possible reaction pathways are discussed.",
author = "Christopher Anastasi and Mark Broomfield and Nielsen, {Ole John} and Palle Pagsberg",
year = "1991",
month = aug,
day = "16",
doi = "10.1016/0009-2614(91)90139-Z",
language = "English",
volume = "182",
pages = "643--648",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "6",

}

RIS

TY - JOUR

T1 - Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals

AU - Anastasi, Christopher

AU - Broomfield, Mark

AU - Nielsen, Ole John

AU - Pagsberg, Palle

PY - 1991/8/16

Y1 - 1991/8/16

N2 - The ultraviolet absorption spectra of CH3S and CH2SH radicals have been measured between 215 and 380 nm using the pulse-radiolysis/kinetic-abso method. One absorption band between 250 and 300 nm and one around 215 nm have been tentatively assigned to the CH2SH and CH3S radicals, respectively. This spectrum has been used to measure the self-reaction rates of these radicals. Rate constants of 4 × 10-11 and 7 × 10-11 cm3 molecule-1 s-1 have been measured at 298 K for CH3S and CH2SH recombination, respectively. The possible reaction pathways are discussed.

AB - The ultraviolet absorption spectra of CH3S and CH2SH radicals have been measured between 215 and 380 nm using the pulse-radiolysis/kinetic-abso method. One absorption band between 250 and 300 nm and one around 215 nm have been tentatively assigned to the CH2SH and CH3S radicals, respectively. This spectrum has been used to measure the self-reaction rates of these radicals. Rate constants of 4 × 10-11 and 7 × 10-11 cm3 molecule-1 s-1 have been measured at 298 K for CH3S and CH2SH recombination, respectively. The possible reaction pathways are discussed.

UR - http://www.scopus.com/inward/record.url?scp=4243811299&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(91)90139-Z

DO - 10.1016/0009-2614(91)90139-Z

M3 - Journal article

AN - SCOPUS:4243811299

VL - 182

SP - 643

EP - 648

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 6

ER -

ID: 228196995