UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase

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UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase. / Wallington, T. J.; Egsgaard, H.; Nielsen, O. J.; Platz, J.; Sehested, J.; Stein, T.

I: Chemical Physics Letters, Bind 290, Nr. 4-6, 01.01.1998, s. 363-370.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Wallington, TJ, Egsgaard, H, Nielsen, OJ, Platz, J, Sehested, J & Stein, T 1998, 'UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase', Chemical Physics Letters, bind 290, nr. 4-6, s. 363-370. https://doi.org/10.1016/S0009-2614(98)00537-5

APA

Wallington, T. J., Egsgaard, H., Nielsen, O. J., Platz, J., Sehested, J., & Stein, T. (1998). UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase. Chemical Physics Letters, 290(4-6), 363-370. https://doi.org/10.1016/S0009-2614(98)00537-5

Vancouver

Wallington TJ, Egsgaard H, Nielsen OJ, Platz J, Sehested J, Stein T. UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase. Chemical Physics Letters. 1998 jan. 1;290(4-6):363-370. https://doi.org/10.1016/S0009-2614(98)00537-5

Author

Wallington, T. J. ; Egsgaard, H. ; Nielsen, O. J. ; Platz, J. ; Sehested, J. ; Stein, T. / UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase. I: Chemical Physics Letters. 1998 ; Bind 290, Nr. 4-6. s. 363-370.

Bibtex

@article{daa2a3e6f3964288b6f472544ceb8452,
title = "UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase",
abstract = "Pulse radiolysis transient UV-visible absorption spectroscopy was used to study the UV-visible absorption spectrum (225-575 nm) of the phenyl radical, C6H5(·), and kinetics of its reaction with NO. Phenyl radicals have a strong broad featureless absorption in the region of 225-340 nm. In the presence of NO phenyl radicals are converted into nitrosobenzene. The phenyl radical spectrum was measured relative to that of nitrosobenzene. Based upon σ(C6H5NO)270 nm = 3.82 × 10-17 cm2 molecule-1 we derive an absorption cross-section for phenyl radicals at 250 nm, σ(C6H5(·))250 nm = (2.75 ± 0.58) × 10-17 cm2 molecule-1. At 295 K in 200-1000 mbar of Ar diluent k(C6H5(·) + NO) = (2.09 ± 0.15) × 10-11 cm3 molecule-1 s-1.",
author = "Wallington, {T. J.} and H. Egsgaard and Nielsen, {O. J.} and J. Platz and J. Sehested and T. Stein",
year = "1998",
month = jan,
day = "1",
doi = "10.1016/S0009-2614(98)00537-5",
language = "English",
volume = "290",
pages = "363--370",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "4-6",

}

RIS

TY - JOUR

T1 - UV-visible spectrum of the phenyl radical and kinetics of its reaction with NO in the gas phase

AU - Wallington, T. J.

AU - Egsgaard, H.

AU - Nielsen, O. J.

AU - Platz, J.

AU - Sehested, J.

AU - Stein, T.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - Pulse radiolysis transient UV-visible absorption spectroscopy was used to study the UV-visible absorption spectrum (225-575 nm) of the phenyl radical, C6H5(·), and kinetics of its reaction with NO. Phenyl radicals have a strong broad featureless absorption in the region of 225-340 nm. In the presence of NO phenyl radicals are converted into nitrosobenzene. The phenyl radical spectrum was measured relative to that of nitrosobenzene. Based upon σ(C6H5NO)270 nm = 3.82 × 10-17 cm2 molecule-1 we derive an absorption cross-section for phenyl radicals at 250 nm, σ(C6H5(·))250 nm = (2.75 ± 0.58) × 10-17 cm2 molecule-1. At 295 K in 200-1000 mbar of Ar diluent k(C6H5(·) + NO) = (2.09 ± 0.15) × 10-11 cm3 molecule-1 s-1.

AB - Pulse radiolysis transient UV-visible absorption spectroscopy was used to study the UV-visible absorption spectrum (225-575 nm) of the phenyl radical, C6H5(·), and kinetics of its reaction with NO. Phenyl radicals have a strong broad featureless absorption in the region of 225-340 nm. In the presence of NO phenyl radicals are converted into nitrosobenzene. The phenyl radical spectrum was measured relative to that of nitrosobenzene. Based upon σ(C6H5NO)270 nm = 3.82 × 10-17 cm2 molecule-1 we derive an absorption cross-section for phenyl radicals at 250 nm, σ(C6H5(·))250 nm = (2.75 ± 0.58) × 10-17 cm2 molecule-1. At 295 K in 200-1000 mbar of Ar diluent k(C6H5(·) + NO) = (2.09 ± 0.15) × 10-11 cm3 molecule-1 s-1.

UR - http://www.scopus.com/inward/record.url?scp=0000057128&partnerID=8YFLogxK

U2 - 10.1016/S0009-2614(98)00537-5

DO - 10.1016/S0009-2614(98)00537-5

M3 - Journal article

AN - SCOPUS:0000057128

VL - 290

SP - 363

EP - 370

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4-6

ER -

ID: 225755328