Atmospheric chemistry of (CF3)2CFOCH3

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Standard

Atmospheric chemistry of (CF3)2CFOCH3. / Andersen, Lene Løffler; Østerstrøm, Freja From; Nielsen, Ole John; Andersen, Mads Peter Sulbæk; Wallington, Timothy J.

I: Chemical Physics Letters, Bind 607, 2014, s. 5-9.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Andersen, LL, Østerstrøm, FF, Nielsen, OJ, Andersen, MPS & Wallington, TJ 2014, 'Atmospheric chemistry of (CF3)2CFOCH3', Chemical Physics Letters, bind 607, s. 5-9. https://doi.org/10.1016/j.cplett.2014.05.036

APA

Andersen, L. L., Østerstrøm, F. F., Nielsen, O. J., Andersen, M. P. S., & Wallington, T. J. (2014). Atmospheric chemistry of (CF3)2CFOCH3. Chemical Physics Letters, 607, 5-9. https://doi.org/10.1016/j.cplett.2014.05.036

Vancouver

Andersen LL, Østerstrøm FF, Nielsen OJ, Andersen MPS, Wallington TJ. Atmospheric chemistry of (CF3)2CFOCH3. Chemical Physics Letters. 2014;607:5-9. https://doi.org/10.1016/j.cplett.2014.05.036

Author

Andersen, Lene Løffler ; Østerstrøm, Freja From ; Nielsen, Ole John ; Andersen, Mads Peter Sulbæk ; Wallington, Timothy J. / Atmospheric chemistry of (CF3)2CFOCH3. I: Chemical Physics Letters. 2014 ; Bind 607. s. 5-9.

Bibtex

@article{350066ef19794efeaf0930ca59a1dd29,
title = "Atmospheric chemistry of (CF3)2CFOCH3",
abstract = "FTIR smog chamber techniques were used to measure k(Cl + (CF 3)2CFOCH3) = (1.80 ± 0.42) × 10-13, k(Cl + (CF3)2CFOCHO) = (1.47 ± 0.56) × 10-14, and k(OH + (CF3) 2CFOCH3) = (1.55 ± 0.24) × 10-14 cm3 molecule-1 s-1. The chlorine-atom initiated oxidation of (CF3)2CFOCH3 in air in the absence of NOX results in conversion of (CF3) 2CFOCH3 into the formate, (CF3) 2CFOCHO, in a yield indistinguishable from 100%. In the presence of NOX, the (CF3)2CFOCHO yield was decreased by approximately 17%, which we attribute to the formation of peroxy and/or alkoxy nitrates. The atmospheric lifetime of (CF3)2CFOCH 3 was estimated to 3.7 years. The infrared spectrum of (CF 3)2CFOCH3 was measured and a global warming potential GWP100 = 354 was determined.",
author = "Andersen, {Lene L{\o}ffler} and {\O}sterstr{\o}m, {Freja From} and Nielsen, {Ole John} and Andersen, {Mads Peter Sulb{\ae}k} and Wallington, {Timothy J.}",
year = "2014",
doi = "10.1016/j.cplett.2014.05.036",
language = "English",
volume = "607",
pages = "5--9",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of (CF3)2CFOCH3

AU - Andersen, Lene Løffler

AU - Østerstrøm, Freja From

AU - Nielsen, Ole John

AU - Andersen, Mads Peter Sulbæk

AU - Wallington, Timothy J.

PY - 2014

Y1 - 2014

N2 - FTIR smog chamber techniques were used to measure k(Cl + (CF 3)2CFOCH3) = (1.80 ± 0.42) × 10-13, k(Cl + (CF3)2CFOCHO) = (1.47 ± 0.56) × 10-14, and k(OH + (CF3) 2CFOCH3) = (1.55 ± 0.24) × 10-14 cm3 molecule-1 s-1. The chlorine-atom initiated oxidation of (CF3)2CFOCH3 in air in the absence of NOX results in conversion of (CF3) 2CFOCH3 into the formate, (CF3) 2CFOCHO, in a yield indistinguishable from 100%. In the presence of NOX, the (CF3)2CFOCHO yield was decreased by approximately 17%, which we attribute to the formation of peroxy and/or alkoxy nitrates. The atmospheric lifetime of (CF3)2CFOCH 3 was estimated to 3.7 years. The infrared spectrum of (CF 3)2CFOCH3 was measured and a global warming potential GWP100 = 354 was determined.

AB - FTIR smog chamber techniques were used to measure k(Cl + (CF 3)2CFOCH3) = (1.80 ± 0.42) × 10-13, k(Cl + (CF3)2CFOCHO) = (1.47 ± 0.56) × 10-14, and k(OH + (CF3) 2CFOCH3) = (1.55 ± 0.24) × 10-14 cm3 molecule-1 s-1. The chlorine-atom initiated oxidation of (CF3)2CFOCH3 in air in the absence of NOX results in conversion of (CF3) 2CFOCH3 into the formate, (CF3) 2CFOCHO, in a yield indistinguishable from 100%. In the presence of NOX, the (CF3)2CFOCHO yield was decreased by approximately 17%, which we attribute to the formation of peroxy and/or alkoxy nitrates. The atmospheric lifetime of (CF3)2CFOCH 3 was estimated to 3.7 years. The infrared spectrum of (CF 3)2CFOCH3 was measured and a global warming potential GWP100 = 354 was determined.

U2 - 10.1016/j.cplett.2014.05.036

DO - 10.1016/j.cplett.2014.05.036

M3 - Journal article

AN - SCOPUS:84901934778

VL - 607

SP - 5

EP - 9

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

ER -

ID: 128738494