Atmospheric Chemistry of CH3CH2OCH3: Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals

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Atmospheric Chemistry of CH3CH2OCH3 : Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals. / Andersen, Mads Peter Sulbæk; Bjørn Svendsen, Sissel ; Østerstrøm, Freja From; Nielsen, Ole John.

I: International Journal of Chemical Kinetics, Bind 49, Nr. 1, 2017, s. 10-20.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Andersen, MPS, Bjørn Svendsen, S, Østerstrøm, FF & Nielsen, OJ 2017, 'Atmospheric Chemistry of CH3CH2OCH3: Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals', International Journal of Chemical Kinetics, bind 49, nr. 1, s. 10-20. https://doi.org/10.1002/kin.21051

APA

Andersen, M. P. S., Bjørn Svendsen, S., Østerstrøm, F. F., & Nielsen, O. J. (2017). Atmospheric Chemistry of CH3CH2OCH3: Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals. International Journal of Chemical Kinetics, 49(1), 10-20. https://doi.org/10.1002/kin.21051

Vancouver

Andersen MPS, Bjørn Svendsen S, Østerstrøm FF, Nielsen OJ. Atmospheric Chemistry of CH3CH2OCH3: Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals. International Journal of Chemical Kinetics. 2017;49(1):10-20. https://doi.org/10.1002/kin.21051

Author

Andersen, Mads Peter Sulbæk ; Bjørn Svendsen, Sissel ; Østerstrøm, Freja From ; Nielsen, Ole John. / Atmospheric Chemistry of CH3CH2OCH3 : Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals. I: International Journal of Chemical Kinetics. 2017 ; Bind 49, Nr. 1. s. 10-20.

Bibtex

@article{a7b9c1cac3b448258284b6d69a842ac8,
title = "Atmospheric Chemistry of CH3CH2OCH3: Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals",
abstract = "The atmospheric chemistry of methyl ethyl ether, CH3CH2OCH3, was examined using FT-IR/relative-rate methods. Hydroxyl radical and chlorine atom rate coefficients of k(CH3CH2OCH3+OH) = (7.53 ± 2.86) × 10−12 cm3 molecule−1 s−1 and k(CH3CH2OCH3+Cl) = (2.35 ± 0.43) × 10−10 cm3 molecule−1 s−1 were determined (297 ± 2 K). The Cl rate coefficient determined here is 30% lower than the previous literature value. The atmospheric lifetime for CH3CH2OCH3 is approximately 2 days. The chlorine atom–initiated oxidation of CH3CH2OCH3 gives CH3C(O)H (9 ± 2%), CH3CH2OC(O)H (29 ± 7%), CH3OC(O)H (19 ± 7%), and CH3C(O)OCH3 (17 ± 7%). The IR absorption cross section for CH3CH2OCH3 is (7.97 ± 0.40) × 10−17 cm molecule−1 (1000–3100 cm−1). CH3CH2OCH3 has a negligible impact on the radiative forcing of climate",
author = "Andersen, {Mads Peter Sulb{\ae}k} and {Bj{\o}rn Svendsen}, Sissel and {\O}sterstr{\o}m, {Freja From} and Nielsen, {Ole John}",
year = "2017",
doi = "10.1002/kin.21051",
language = "English",
volume = "49",
pages = "10--20",
journal = "International Journal of Chemical Kinetics",
issn = "0538-8066",
publisher = "JohnWiley & Sons, Inc.",
number = "1",

}

RIS

TY - JOUR

T1 - Atmospheric Chemistry of CH3CH2OCH3

T2 - Kinetics and Mechanism of Reactions with Cl Atoms and OH Radicals

AU - Andersen, Mads Peter Sulbæk

AU - Bjørn Svendsen, Sissel

AU - Østerstrøm, Freja From

AU - Nielsen, Ole John

PY - 2017

Y1 - 2017

N2 - The atmospheric chemistry of methyl ethyl ether, CH3CH2OCH3, was examined using FT-IR/relative-rate methods. Hydroxyl radical and chlorine atom rate coefficients of k(CH3CH2OCH3+OH) = (7.53 ± 2.86) × 10−12 cm3 molecule−1 s−1 and k(CH3CH2OCH3+Cl) = (2.35 ± 0.43) × 10−10 cm3 molecule−1 s−1 were determined (297 ± 2 K). The Cl rate coefficient determined here is 30% lower than the previous literature value. The atmospheric lifetime for CH3CH2OCH3 is approximately 2 days. The chlorine atom–initiated oxidation of CH3CH2OCH3 gives CH3C(O)H (9 ± 2%), CH3CH2OC(O)H (29 ± 7%), CH3OC(O)H (19 ± 7%), and CH3C(O)OCH3 (17 ± 7%). The IR absorption cross section for CH3CH2OCH3 is (7.97 ± 0.40) × 10−17 cm molecule−1 (1000–3100 cm−1). CH3CH2OCH3 has a negligible impact on the radiative forcing of climate

AB - The atmospheric chemistry of methyl ethyl ether, CH3CH2OCH3, was examined using FT-IR/relative-rate methods. Hydroxyl radical and chlorine atom rate coefficients of k(CH3CH2OCH3+OH) = (7.53 ± 2.86) × 10−12 cm3 molecule−1 s−1 and k(CH3CH2OCH3+Cl) = (2.35 ± 0.43) × 10−10 cm3 molecule−1 s−1 were determined (297 ± 2 K). The Cl rate coefficient determined here is 30% lower than the previous literature value. The atmospheric lifetime for CH3CH2OCH3 is approximately 2 days. The chlorine atom–initiated oxidation of CH3CH2OCH3 gives CH3C(O)H (9 ± 2%), CH3CH2OC(O)H (29 ± 7%), CH3OC(O)H (19 ± 7%), and CH3C(O)OCH3 (17 ± 7%). The IR absorption cross section for CH3CH2OCH3 is (7.97 ± 0.40) × 10−17 cm molecule−1 (1000–3100 cm−1). CH3CH2OCH3 has a negligible impact on the radiative forcing of climate

U2 - 10.1002/kin.21051

DO - 10.1002/kin.21051

M3 - Journal article

VL - 49

SP - 10

EP - 20

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

SN - 0538-8066

IS - 1

ER -

ID: 176367410