Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3

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Standard

Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3. / Andersen, Mads Peter Sulbæk; Nilsson, E. J. K.; Nielsen, O. J.; Johnson, M. S.; Hurley, M. D.; Wallington, T. J.

I: Journal of Photochemistry and Photobiology, A: Chemistry, Bind 199, Nr. 1, 2008, s. 92-97.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Andersen, MPS, Nilsson, EJK, Nielsen, OJ, Johnson, MS, Hurley, MD & Wallington, TJ 2008, 'Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3', Journal of Photochemistry and Photobiology, A: Chemistry, bind 199, nr. 1, s. 92-97. https://doi.org/10.1016/j.jphotochem.2008.05.013

APA

Andersen, M. P. S., Nilsson, E. J. K., Nielsen, O. J., Johnson, M. S., Hurley, M. D., & Wallington, T. J. (2008). Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3. Journal of Photochemistry and Photobiology, A: Chemistry, 199(1), 92-97. https://doi.org/10.1016/j.jphotochem.2008.05.013

Vancouver

Andersen MPS, Nilsson EJK, Nielsen OJ, Johnson MS, Hurley MD, Wallington TJ. Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3. Journal of Photochemistry and Photobiology, A: Chemistry. 2008;199(1):92-97. https://doi.org/10.1016/j.jphotochem.2008.05.013

Author

Andersen, Mads Peter Sulbæk ; Nilsson, E. J. K. ; Nielsen, O. J. ; Johnson, M. S. ; Hurley, M. D. ; Wallington, T. J. / Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3. I: Journal of Photochemistry and Photobiology, A: Chemistry. 2008 ; Bind 199, Nr. 1. s. 92-97.

Bibtex

@article{451f17159f25418c910f11eea216f2a9,
title = "Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3",
abstract = "Long path length Fourier transform infrared (FTIR)-smog chamber techniques were used to study the kinetics of the gas-phase reactions of Cl atoms. OH radicals and O-3 with trans-3,3,3-trifluoro-1-chloropropene, t-CF3CH = CHCl, in 700Torr total pressure at 295 +/- 2 K. Values of k(Cl + t-CF3CH = CHCl) = (5.22 +/- 0.72) x 10(-11) cm(3) molecule(-1) s(-1), k(OH + t-CF3CH = CHCl) = (4.40 +/- 0.38) x 10(-13) cm(3) molecule(-1) s(-1) and k(O-3 + t-CF3CH = CHCl) = (1.46 +/- 0.12) x 10(-21) cm(3) molecule(-1) s(-1), were established (quoted uncertainties are 2 sigma: see Experimental section). The IR spectrum of t-CF3CH = CHCl is reported. The atmospheric lifetime of t-CF3CH = CHCl is determined by reaction with OH radicals and is approximately 26 days. The global warming potential of t-CF3CH = CHCl is approximately 7 for a 100-year time horizon. (C) 2008 Elsevier B.V. All rights reserved.",
author = "Andersen, {Mads Peter Sulb{\ae}k} and Nilsson, {E. J. K.} and Nielsen, {O. J.} and Johnson, {M. S.} and Hurley, {M. D.} and Wallington, {T. J.}",
year = "2008",
doi = "10.1016/j.jphotochem.2008.05.013",
language = "English",
volume = "199",
pages = "92--97",
journal = "Journal of Photochemistry and Photobiology, A: Chemistry",
issn = "1010-6030",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of trans-CF3CH = CHCl: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O-3

AU - Andersen, Mads Peter Sulbæk

AU - Nilsson, E. J. K.

AU - Nielsen, O. J.

AU - Johnson, M. S.

AU - Hurley, M. D.

AU - Wallington, T. J.

PY - 2008

Y1 - 2008

N2 - Long path length Fourier transform infrared (FTIR)-smog chamber techniques were used to study the kinetics of the gas-phase reactions of Cl atoms. OH radicals and O-3 with trans-3,3,3-trifluoro-1-chloropropene, t-CF3CH = CHCl, in 700Torr total pressure at 295 +/- 2 K. Values of k(Cl + t-CF3CH = CHCl) = (5.22 +/- 0.72) x 10(-11) cm(3) molecule(-1) s(-1), k(OH + t-CF3CH = CHCl) = (4.40 +/- 0.38) x 10(-13) cm(3) molecule(-1) s(-1) and k(O-3 + t-CF3CH = CHCl) = (1.46 +/- 0.12) x 10(-21) cm(3) molecule(-1) s(-1), were established (quoted uncertainties are 2 sigma: see Experimental section). The IR spectrum of t-CF3CH = CHCl is reported. The atmospheric lifetime of t-CF3CH = CHCl is determined by reaction with OH radicals and is approximately 26 days. The global warming potential of t-CF3CH = CHCl is approximately 7 for a 100-year time horizon. (C) 2008 Elsevier B.V. All rights reserved.

AB - Long path length Fourier transform infrared (FTIR)-smog chamber techniques were used to study the kinetics of the gas-phase reactions of Cl atoms. OH radicals and O-3 with trans-3,3,3-trifluoro-1-chloropropene, t-CF3CH = CHCl, in 700Torr total pressure at 295 +/- 2 K. Values of k(Cl + t-CF3CH = CHCl) = (5.22 +/- 0.72) x 10(-11) cm(3) molecule(-1) s(-1), k(OH + t-CF3CH = CHCl) = (4.40 +/- 0.38) x 10(-13) cm(3) molecule(-1) s(-1) and k(O-3 + t-CF3CH = CHCl) = (1.46 +/- 0.12) x 10(-21) cm(3) molecule(-1) s(-1), were established (quoted uncertainties are 2 sigma: see Experimental section). The IR spectrum of t-CF3CH = CHCl is reported. The atmospheric lifetime of t-CF3CH = CHCl is determined by reaction with OH radicals and is approximately 26 days. The global warming potential of t-CF3CH = CHCl is approximately 7 for a 100-year time horizon. (C) 2008 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.jphotochem.2008.05.013

DO - 10.1016/j.jphotochem.2008.05.013

M3 - Journal article

VL - 199

SP - 92

EP - 97

JO - Journal of Photochemistry and Photobiology, A: Chemistry

JF - Journal of Photochemistry and Photobiology, A: Chemistry

SN - 1010-6030

IS - 1

ER -

ID: 44568053