CO2 (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases

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Standard

CO2 (De)Activation in Carboxylation Reactions : A Case Study Using Grignard Reagents and Nucleophilic Bases. / Valera Lauridsen, Jerik Mathew; Cho, Sung Yeon; Bae, Han Yong; Lee, Ji-Woong.

I: Organometallics, 2020, s. 1652–1657.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Valera Lauridsen, JM, Cho, SY, Bae, HY & Lee, J-W 2020, 'CO2 (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases', Organometallics, s. 1652–1657. https://doi.org/10.1021/acs.organomet.9b00838

APA

Valera Lauridsen, J. M., Cho, S. Y., Bae, H. Y., & Lee, J-W. (2020). CO2 (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases. Organometallics, 1652–1657. https://doi.org/10.1021/acs.organomet.9b00838

Vancouver

Valera Lauridsen JM, Cho SY, Bae HY, Lee J-W. CO2 (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases. Organometallics. 2020;1652–1657. https://doi.org/10.1021/acs.organomet.9b00838

Author

Valera Lauridsen, Jerik Mathew ; Cho, Sung Yeon ; Bae, Han Yong ; Lee, Ji-Woong. / CO2 (De)Activation in Carboxylation Reactions : A Case Study Using Grignard Reagents and Nucleophilic Bases. I: Organometallics. 2020 ; s. 1652–1657.

Bibtex

@article{5d48870988d44bbc96063b6d447a4dbf,
title = "CO2 (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases",
abstract = "Carbon dioxide (CO2) is an intrinsically stable molecule. However, its reactivity toward nucleophilic bases has constituted an appealing characteristic for applications such as CO2 capture and functionalization. To shed light on the role of nucleophilic bases in CO2 functionalization, we performed some mechanistic studies using nitrogen-containing bases as an additive—in catalytic amounts—for carboxylation reactions of Grignard reagents. Our kinetic analysis and in situ infrared spectroscopy revealed the role of nucleophilic bases, particularly that of DBU (1,8-diazabicycloundec-7-ene), in CO2 (de)activation for carboxylation reactions.",
author = "{Valera Lauridsen}, {Jerik Mathew} and Cho, {Sung Yeon} and Bae, {Han Yong} and Ji-Woong Lee",
note = "doi: 10.1021/acs.organomet.9b00838",
year = "2020",
doi = "10.1021/acs.organomet.9b00838",
language = "English",
pages = "1652–1657",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",

}

RIS

TY - JOUR

T1 - CO2 (De)Activation in Carboxylation Reactions

T2 - A Case Study Using Grignard Reagents and Nucleophilic Bases

AU - Valera Lauridsen, Jerik Mathew

AU - Cho, Sung Yeon

AU - Bae, Han Yong

AU - Lee, Ji-Woong

N1 - doi: 10.1021/acs.organomet.9b00838

PY - 2020

Y1 - 2020

N2 - Carbon dioxide (CO2) is an intrinsically stable molecule. However, its reactivity toward nucleophilic bases has constituted an appealing characteristic for applications such as CO2 capture and functionalization. To shed light on the role of nucleophilic bases in CO2 functionalization, we performed some mechanistic studies using nitrogen-containing bases as an additive—in catalytic amounts—for carboxylation reactions of Grignard reagents. Our kinetic analysis and in situ infrared spectroscopy revealed the role of nucleophilic bases, particularly that of DBU (1,8-diazabicycloundec-7-ene), in CO2 (de)activation for carboxylation reactions.

AB - Carbon dioxide (CO2) is an intrinsically stable molecule. However, its reactivity toward nucleophilic bases has constituted an appealing characteristic for applications such as CO2 capture and functionalization. To shed light on the role of nucleophilic bases in CO2 functionalization, we performed some mechanistic studies using nitrogen-containing bases as an additive—in catalytic amounts—for carboxylation reactions of Grignard reagents. Our kinetic analysis and in situ infrared spectroscopy revealed the role of nucleophilic bases, particularly that of DBU (1,8-diazabicycloundec-7-ene), in CO2 (de)activation for carboxylation reactions.

U2 - 10.1021/acs.organomet.9b00838

DO - 10.1021/acs.organomet.9b00838

M3 - Journal article

SP - 1652

EP - 1657

JO - Organometallics

JF - Organometallics

SN - 0276-7333

ER -

ID: 237704789