Counterions control whether self-assembly leads to formation of stable and well-defined unilamellar nanotubes or nanoribbons and nanorods
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Counterions control whether self-assembly leads to formation of stable and well-defined unilamellar nanotubes or nanoribbons and nanorods. / Shi, Dong; Schwall, Christian; Sfintes, George; Thyrhaug, Erling; Hammershøj, Peter; Cardenas Gomez, Marite; Simonsen, Jens Bæk; Laursen, Bo Wegge.
I: Chemistry: A European Journal, Bind 20, Nr. 23, 2014, s. 6853-6856.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Counterions control whether self-assembly leads to formation of stable and well-defined unilamellar nanotubes or nanoribbons and nanorods
AU - Shi, Dong
AU - Schwall, Christian
AU - Sfintes, George
AU - Thyrhaug, Erling
AU - Hammershøj, Peter
AU - Cardenas Gomez, Marite
AU - Simonsen, Jens Bæk
AU - Laursen, Bo Wegge
N1 - © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2014
Y1 - 2014
N2 - Self-assembly of the amphiphilic π-conjugated carbenium ion ATOTA-1(+) in aqueous solution selectively leads to discrete and highly stable nanotubes or nanoribbons and nanorods, depending on the nature of the counterion (Cl(-) vs. PF6(-), respectively). The nanotubes formed by the Cl(-) salt illustrate an exceptional example of a structural well-defined (29±2 nm in outer diameter) unilamellar tubular morphology featuring π-conjugated functionality and high stability and flexibility, in aqueous solution.
AB - Self-assembly of the amphiphilic π-conjugated carbenium ion ATOTA-1(+) in aqueous solution selectively leads to discrete and highly stable nanotubes or nanoribbons and nanorods, depending on the nature of the counterion (Cl(-) vs. PF6(-), respectively). The nanotubes formed by the Cl(-) salt illustrate an exceptional example of a structural well-defined (29±2 nm in outer diameter) unilamellar tubular morphology featuring π-conjugated functionality and high stability and flexibility, in aqueous solution.
U2 - 10.1002/chem.201402523
DO - 10.1002/chem.201402523
M3 - Journal article
C2 - 24806100
VL - 20
SP - 6853
EP - 6856
JO - Chemistry: A European Journal
JF - Chemistry: A European Journal
SN - 0947-6539
IS - 23
ER -
ID: 130898505