Efficient dechlorination of carbon tetrachloride by hydrophobic green rust intercalated with dodecanoate anions
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Efficient dechlorination of carbon tetrachloride by hydrophobic green rust intercalated with dodecanoate anions. / Ayala Luis, Karina Barbara; Ginette Anneliese Cooper, Nicola; Bender Koch, Christian; Hansen, Hans Chr. Bruun.
I: Environmental Science & Technology (Washington), Bind 46, Nr. 6, 2012, s. 3390-3397.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Efficient dechlorination of carbon tetrachloride by hydrophobic green rust intercalated with dodecanoate anions
AU - Ayala Luis, Karina Barbara
AU - Ginette Anneliese Cooper, Nicola
AU - Bender Koch, Christian
AU - Hansen, Hans Chr. Bruun
PY - 2012
Y1 - 2012
N2 - The reductive dechlorination of carbon tetrachloride (CT) by Fe-II-Fe-III hydroxide (green rust) intercalated with dodecanoate, (Fe4Fe2III)-Fe-II (OH)(12)(C12H23O2)(2)center dot gamma H2O (designated GR(C12)), at pH similar to 8 and at room temperature was investigated. CT at concentration levels similar to those found in heavily contaminated groundwater close to polluted industrial sites (14 988 mu M) was reduced mainly to the fully dechlorinated products carbon monoxide (CO, yields >54 and formic acid (HCOOH, yields >6. Minor formation of chloroform (CF), the only chlorinated degradation product, was also detected (yields
AB - The reductive dechlorination of carbon tetrachloride (CT) by Fe-II-Fe-III hydroxide (green rust) intercalated with dodecanoate, (Fe4Fe2III)-Fe-II (OH)(12)(C12H23O2)(2)center dot gamma H2O (designated GR(C12)), at pH similar to 8 and at room temperature was investigated. CT at concentration levels similar to those found in heavily contaminated groundwater close to polluted industrial sites (14 988 mu M) was reduced mainly to the fully dechlorinated products carbon monoxide (CO, yields >54 and formic acid (HCOOH, yields >6. Minor formation of chloroform (CF), the only chlorinated degradation product, was also detected (yields
U2 - 10.1021/es204368u
DO - 10.1021/es204368u
M3 - Journal article
C2 - 22360442
VL - 46
SP - 3390
EP - 3397
JO - Environmental Science & Technology
JF - Environmental Science & Technology
SN - 0013-936X
IS - 6
ER -
ID: 43667477