Microwave-assisted McMurry polymerization utilizing low-valent titanium for the synthesis of poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] (PNV)
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Microwave-assisted McMurry polymerization utilizing low-valent titanium for the synthesis of poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] (PNV). / Thomas, Henrik; Stuhr-Hansen, Nicolai; Westerlund, Axel Rune Fredrik; Laursen, Bo Wegge; Magnussen, Magnus Jesper; Sørensen, Henning O.; Bjørnholm, Thomas; Christensen, Jørn Bolstad.
I: Tetrahedron Letters, Bind 50, Nr. 52, 2009, s. 7374-7378.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Microwave-assisted McMurry polymerization utilizing low-valent titanium for the synthesis of poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] (PNV)
AU - Thomas, Henrik
AU - Stuhr-Hansen, Nicolai
AU - Westerlund, Axel Rune Fredrik
AU - Laursen, Bo Wegge
AU - Magnussen, Magnus Jesper
AU - Sørensen, Henning O.
AU - Bjørnholm, Thomas
AU - Christensen, Jørn Bolstad
PY - 2009
Y1 - 2009
N2 - Poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] is synthesized by microwave-assisted McMurry polymerization utilizing low-valent titanium generated from titanium tetrachloride and zinc. The obtained polymer is fluorescent with an average molecular weight of approximately 65,000 g/mol and a polydispersity of M-w/M-n approximate to 3. Absorption and fluorescence spectroscopy in solution and on spin-cast thin films reveal that the bis-alkoxy substituted PNV has a short effective Conjugation length but a quite efficient exciton migration. (C) 2009 Elsevier Ltd. All rights reserved.
AB - Poly 2,6-[1,5-bis(dodecyloxy)naphthylene vinylene] is synthesized by microwave-assisted McMurry polymerization utilizing low-valent titanium generated from titanium tetrachloride and zinc. The obtained polymer is fluorescent with an average molecular weight of approximately 65,000 g/mol and a polydispersity of M-w/M-n approximate to 3. Absorption and fluorescence spectroscopy in solution and on spin-cast thin films reveal that the bis-alkoxy substituted PNV has a short effective Conjugation length but a quite efficient exciton migration. (C) 2009 Elsevier Ltd. All rights reserved.
U2 - 10.1016/j.tetlet.2009.10.083
DO - 10.1016/j.tetlet.2009.10.083
M3 - Journal article
VL - 50
SP - 7374
EP - 7378
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 52
ER -
ID: 16158187