Synthesis of redox-active donor/acceptor chromophores with a central indenofluorene or indacenodithiophene core
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Synthesis of redox-active donor/acceptor chromophores with a central indenofluorene or indacenodithiophene core. / Andersen, Dianna; Nygaard, David Bo; Kragh, Rasmus Refsgaard; Broløs, Line; Nielsen, Mogens Brøndsted.
I: Tetrahedron Letters, Bind 61, Nr. 23, 151939, 01.06.2020.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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T1 - Synthesis of redox-active donor/acceptor chromophores with a central indenofluorene or indacenodithiophene core
AU - Andersen, Dianna
AU - Nygaard, David Bo
AU - Kragh, Rasmus Refsgaard
AU - Broløs, Line
AU - Nielsen, Mogens Brøndsted
PY - 2020/6/1
Y1 - 2020/6/1
N2 - Tetrathiafulvalene (TTF) and tetracyanoquinodimethane (TCNQ) are classical redox-active molecules that can be oxidized and reduced, respectively, in two one-electron steps. Herein we present the synthesis of a selection of extended derivatives based on either an indenofluorene or indacenodithiophene core and containing either two dithiafulvene units (extended TTF), two dicyanomethylene units (extended TCNQ) or one of each of these units (donor–acceptor system). The optical and redox properties of the molecules are also presented.
AB - Tetrathiafulvalene (TTF) and tetracyanoquinodimethane (TCNQ) are classical redox-active molecules that can be oxidized and reduced, respectively, in two one-electron steps. Herein we present the synthesis of a selection of extended derivatives based on either an indenofluorene or indacenodithiophene core and containing either two dithiafulvene units (extended TTF), two dicyanomethylene units (extended TCNQ) or one of each of these units (donor–acceptor system). The optical and redox properties of the molecules are also presented.
U2 - 10.1016/j.tetlet.2020.151939
DO - 10.1016/j.tetlet.2020.151939
M3 - Journal article
VL - 61
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 23
M1 - 151939
ER -
ID: 242663118