The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems

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Standard

The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems. / Kjeldsen, Ida Lützen Hoff; Høvring, Julie Franck; Von Buchwald, Theo Juncker; Hillers-bendtsen, Andreas Erbs; Mikkelsen, Kurt V.

I: Physical Chemistry Chemical Physics, Bind 24, Nr. 9, 2022, s. 5564–5577.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Kjeldsen, ILH, Høvring, JF, Von Buchwald, TJ, Hillers-bendtsen, AE & Mikkelsen, KV 2022, 'The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems', Physical Chemistry Chemical Physics, bind 24, nr. 9, s. 5564–5577. https://doi.org/10.1039/D2CP00401A

APA

Kjeldsen, I. L. H., Høvring, J. F., Von Buchwald, T. J., Hillers-bendtsen, A. E., & Mikkelsen, K. V. (2022). The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems. Physical Chemistry Chemical Physics, 24(9), 5564–5577. https://doi.org/10.1039/D2CP00401A

Vancouver

Kjeldsen ILH, Høvring JF, Von Buchwald TJ, Hillers-bendtsen AE, Mikkelsen KV. The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems. Physical Chemistry Chemical Physics. 2022;24(9):5564–5577. https://doi.org/10.1039/D2CP00401A

Author

Kjeldsen, Ida Lützen Hoff ; Høvring, Julie Franck ; Von Buchwald, Theo Juncker ; Hillers-bendtsen, Andreas Erbs ; Mikkelsen, Kurt V. / The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems. I: Physical Chemistry Chemical Physics. 2022 ; Bind 24, Nr. 9. s. 5564–5577.

Bibtex

@article{4e64301feece4c8fb808f8f4604246d2,
title = "The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems",
abstract = "Solvent effects on molecular solar thermal energy storage systems have been investigated using density functional theory combined with solvent models describing the effects of viscosities and dielectric constants on chemical reaction rates. We have addressed the following issues concerning how solvents influence both the thermochemical properties and the thermal relaxation kinetics of the studied systems, how the friction of the solvent influences the recrossing of the reactions along with the dynamics and force constants of the transition state. We observe that the rate constants for the chemical reactions of the molecular solar thermal energy storage systems depend strongly on the dielectric solvent properties and the viscosities of the solvents.",
author = "Kjeldsen, {Ida L{\"u}tzen Hoff} and H{\o}vring, {Julie Franck} and {Von Buchwald}, {Theo Juncker} and Hillers-bendtsen, {Andreas Erbs} and Mikkelsen, {Kurt V.}",
year = "2022",
doi = "10.1039/D2CP00401A",
language = "English",
volume = "24",
pages = "5564–5577",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "9",

}

RIS

TY - JOUR

T1 - The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems

AU - Kjeldsen, Ida Lützen Hoff

AU - Høvring, Julie Franck

AU - Von Buchwald, Theo Juncker

AU - Hillers-bendtsen, Andreas Erbs

AU - Mikkelsen, Kurt V.

PY - 2022

Y1 - 2022

N2 - Solvent effects on molecular solar thermal energy storage systems have been investigated using density functional theory combined with solvent models describing the effects of viscosities and dielectric constants on chemical reaction rates. We have addressed the following issues concerning how solvents influence both the thermochemical properties and the thermal relaxation kinetics of the studied systems, how the friction of the solvent influences the recrossing of the reactions along with the dynamics and force constants of the transition state. We observe that the rate constants for the chemical reactions of the molecular solar thermal energy storage systems depend strongly on the dielectric solvent properties and the viscosities of the solvents.

AB - Solvent effects on molecular solar thermal energy storage systems have been investigated using density functional theory combined with solvent models describing the effects of viscosities and dielectric constants on chemical reaction rates. We have addressed the following issues concerning how solvents influence both the thermochemical properties and the thermal relaxation kinetics of the studied systems, how the friction of the solvent influences the recrossing of the reactions along with the dynamics and force constants of the transition state. We observe that the rate constants for the chemical reactions of the molecular solar thermal energy storage systems depend strongly on the dielectric solvent properties and the viscosities of the solvents.

U2 - 10.1039/D2CP00401A

DO - 10.1039/D2CP00401A

M3 - Journal article

VL - 24

SP - 5564

EP - 5577

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 9

ER -

ID: 298471491