The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches

Publikation: Bidrag til tidsskrift › Review › Forskning › fagfællebedømt

Standard

The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches. / Gertsen , Anders S. ; Mikkelsen, Kurt Valentin.

I: Japan Journal of Research, Bind 4, Nr. 6, 2023.

Publikation: Bidrag til tidsskrift › Review › Forskning › fagfællebedømt

Harvard

Gertsen , AS & Mikkelsen, KV 2023, 'The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches', Japan Journal of Research, bind 4, nr. 6. https://doi.org/10.33425/2690-8077.1078

APA

Gertsen , A. S., & Mikkelsen, K. V. (2023). The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches. Japan Journal of Research, 4(6). https://doi.org/10.33425/2690-8077.1078

Vancouver

Gertsen AS, Mikkelsen KV. The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches. Japan Journal of Research. 2023;4(6). https://doi.org/10.33425/2690-8077.1078

Author

Gertsen , Anders S. ; Mikkelsen, Kurt Valentin. / The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches. I: Japan Journal of Research. 2023 ; Bind 4, Nr. 6.

Bibtex

@article{1e569b79a9134551b59ba0ee157cf358,
title = "The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches",
abstract = "We have investigated the switching mechanisms of photochromic systems that are relevant for harvesting,storing, and releasing solar energy. We consider storage of solar energy in the form of energeticchemical bonds via light-induced isomerization reactions. The approach concerns photoswitches thatupon irradiation isomerize to high-energy metastable isomers and through the corresponding back-reaction will release the stored energy. Thereby, we have considered molecular closed-cycle energystorage systems that do not involve the release of CO2. We present potential energy surfaces for groundstates and excited states and discuss the roles that these states play when harvesting, storing, andreleasing solar energy. Furthermore, we have illustrated new approaches for obtaining synergy betweentheoretical modeling and future experimental work.",
author = "Gertsen, {Anders S.} and Mikkelsen, {Kurt Valentin}",
year = "2023",
doi = "10.33425/2690-8077.1078",
language = "English",
volume = "4",
journal = "Japan Journal of Research",
issn = "2690-8077",
number = "6",

}

RIS

TY - JOUR

T1 - The Switching Mechanisms of Dihydroazulene /Vinylheptafulvene Photo-/Thermoswitches

AU - Gertsen , Anders S.

AU - Mikkelsen, Kurt Valentin

PY - 2023

Y1 - 2023

N2 - We have investigated the switching mechanisms of photochromic systems that are relevant for harvesting,storing, and releasing solar energy. We consider storage of solar energy in the form of energeticchemical bonds via light-induced isomerization reactions. The approach concerns photoswitches thatupon irradiation isomerize to high-energy metastable isomers and through the corresponding back-reaction will release the stored energy. Thereby, we have considered molecular closed-cycle energystorage systems that do not involve the release of CO2. We present potential energy surfaces for groundstates and excited states and discuss the roles that these states play when harvesting, storing, andreleasing solar energy. Furthermore, we have illustrated new approaches for obtaining synergy betweentheoretical modeling and future experimental work.

AB - We have investigated the switching mechanisms of photochromic systems that are relevant for harvesting,storing, and releasing solar energy. We consider storage of solar energy in the form of energeticchemical bonds via light-induced isomerization reactions. The approach concerns photoswitches thatupon irradiation isomerize to high-energy metastable isomers and through the corresponding back-reaction will release the stored energy. Thereby, we have considered molecular closed-cycle energystorage systems that do not involve the release of CO2. We present potential energy surfaces for groundstates and excited states and discuss the roles that these states play when harvesting, storing, andreleasing solar energy. Furthermore, we have illustrated new approaches for obtaining synergy betweentheoretical modeling and future experimental work.

U2 - 10.33425/2690-8077.1078

DO - 10.33425/2690-8077.1078

M3 - Review

VL - 4

JO - Japan Journal of Research

JF - Japan Journal of Research

SN - 2690-8077

IS - 6

ER -

ID: 383028754