Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals

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Standard

Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals. / Møgelberg, Trine E.; Nielsen, Ole J.; Sehested, Jens; Wallington, Timothy J.; Hurley, Michael D.

I: Chemical Physics Letters, Bind 226, Nr. 1-2, 12.08.1994, s. 171-177.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Møgelberg, TE, Nielsen, OJ, Sehested, J, Wallington, TJ & Hurley, MD 1994, 'Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals', Chemical Physics Letters, bind 226, nr. 1-2, s. 171-177. https://doi.org/10.1016/0009-2614(94)00692-X

APA

Møgelberg, T. E., Nielsen, O. J., Sehested, J., Wallington, T. J., & Hurley, M. D. (1994). Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals. Chemical Physics Letters, 226(1-2), 171-177. https://doi.org/10.1016/0009-2614(94)00692-X

Vancouver

Møgelberg TE, Nielsen OJ, Sehested J, Wallington TJ, Hurley MD. Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals. Chemical Physics Letters. 1994 aug. 12;226(1-2):171-177. https://doi.org/10.1016/0009-2614(94)00692-X

Author

Møgelberg, Trine E. ; Nielsen, Ole J. ; Sehested, Jens ; Wallington, Timothy J. ; Hurley, Michael D. / Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals. I: Chemical Physics Letters. 1994 ; Bind 226, Nr. 1-2. s. 171-177.

Bibtex

@article{17a194a9ebe44abf8f4def59f9a597d1,
title = "Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals",
abstract = "Two different experimental techniques were used to study the kinetics of the reaction of OH radicals with trifluoroacetic acid, CF3COOH. Using a pulse radiolysis absolute rate technique, rate constants at 315 and 348 K were determined to be (1.6±0.4)×10-13 and (1.5±0.2)×10-13 cm3 molecule-1 s-1, respectively. Using a long path-length FTIR relative rate technique a rate constant of (1.7±0.5)×10-13 cm3 molecule-1 s-1 was obtained at 296 K. In the atmosphere, reaction with OH radicals in the gas phase is estimated to account for 10%-20% of the loss of CF3COOH. The major fate of CF3COOH is rainout.",
author = "M{\o}gelberg, {Trine E.} and Nielsen, {Ole J.} and Jens Sehested and Wallington, {Timothy J.} and Hurley, {Michael D.}",
year = "1994",
month = aug,
day = "12",
doi = "10.1016/0009-2614(94)00692-X",
language = "English",
volume = "226",
pages = "171--177",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of CF3COOH. Kinetics of the reaction with OH radicals

AU - Møgelberg, Trine E.

AU - Nielsen, Ole J.

AU - Sehested, Jens

AU - Wallington, Timothy J.

AU - Hurley, Michael D.

PY - 1994/8/12

Y1 - 1994/8/12

N2 - Two different experimental techniques were used to study the kinetics of the reaction of OH radicals with trifluoroacetic acid, CF3COOH. Using a pulse radiolysis absolute rate technique, rate constants at 315 and 348 K were determined to be (1.6±0.4)×10-13 and (1.5±0.2)×10-13 cm3 molecule-1 s-1, respectively. Using a long path-length FTIR relative rate technique a rate constant of (1.7±0.5)×10-13 cm3 molecule-1 s-1 was obtained at 296 K. In the atmosphere, reaction with OH radicals in the gas phase is estimated to account for 10%-20% of the loss of CF3COOH. The major fate of CF3COOH is rainout.

AB - Two different experimental techniques were used to study the kinetics of the reaction of OH radicals with trifluoroacetic acid, CF3COOH. Using a pulse radiolysis absolute rate technique, rate constants at 315 and 348 K were determined to be (1.6±0.4)×10-13 and (1.5±0.2)×10-13 cm3 molecule-1 s-1, respectively. Using a long path-length FTIR relative rate technique a rate constant of (1.7±0.5)×10-13 cm3 molecule-1 s-1 was obtained at 296 K. In the atmosphere, reaction with OH radicals in the gas phase is estimated to account for 10%-20% of the loss of CF3COOH. The major fate of CF3COOH is rainout.

UR - http://www.scopus.com/inward/record.url?scp=0342673116&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(94)00692-X

DO - 10.1016/0009-2614(94)00692-X

M3 - Journal article

AN - SCOPUS:0342673116

VL - 226

SP - 171

EP - 177

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-2

ER -

ID: 228193014