Atmospheric chemistry of FNO and FNO2: Reactions of FNO with O3, O(3P), HO2, and HCl and the reaction of FNO2 with O3
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Upper limits for the rate constants of the following gas phase reactions have been determined at 296 K: k(FNO+O3) < 3 × 10-18, k(FNO+O(3P)) < 5 × 10-13, k(FNO+HO2) < 3 × 10-12, k(FNO+HCl) < 5 × 10-18, and k(FNO2+O3) < 8 × 10-19 cm3 molecule-1 s-1. These reactions can be ruled out as chain or sink reactions of FNO in the atmosphere. The implications for the atmospheric chemistry of FNO are discussed.
Originalsprog | Engelsk |
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Tidsskrift | Journal of Physical Chemistry |
Vol/bind | 99 |
Udgave nummer | 3 |
Sider (fra-til) | 984-989 |
Antal sider | 6 |
ISSN | 0022-3654 |
Status | Udgivet - 1 dec. 1995 |
ID: 228192582