Rate Constants for the Gas-Phase Reactions of Hydroxyl Radicals with Tetramethyllead and Tetraethyllead
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Rate Constants for the Gas-Phase Reactions of Hydroxyl Radicals with Tetramethyllead and Tetraethyllead. / Nielsen, Ole John; O’Farrell, Denis J.; Treacy, Jack J.; Sldebottom, Howard W.
I: Environmental Science and Technology, Bind 25, Nr. 6, 01.06.1991, s. 1098-1103.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Rate Constants for the Gas-Phase Reactions of Hydroxyl Radicals with Tetramethyllead and Tetraethyllead
AU - Nielsen, Ole John
AU - O’Farrell, Denis J.
AU - Treacy, Jack J.
AU - Sldebottom, Howard W.
PY - 1991/6/1
Y1 - 1991/6/1
N2 - Rate constants for the reactions of OH radicals with (CH3)4Pb and (C2H5)4Pb have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. Rate data were obtained by using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. Rate constants were also obtained for the analogous reactions with (CH3)4C and (C2H5)4C for comparison purposes. The results are discussed in terms of structure-reactivity relationships. Values of the rate constants (10-12 cm3 molecule-1 s-1) are [formula omited].
AB - Rate constants for the reactions of OH radicals with (CH3)4Pb and (C2H5)4Pb have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. Rate data were obtained by using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a conventional photolytic relative rate method. Rate constants were also obtained for the analogous reactions with (CH3)4C and (C2H5)4C for comparison purposes. The results are discussed in terms of structure-reactivity relationships. Values of the rate constants (10-12 cm3 molecule-1 s-1) are [formula omited].
UR - http://www.scopus.com/inward/record.url?scp=0025758957&partnerID=8YFLogxK
U2 - 10.1021/es00018a013
DO - 10.1021/es00018a013
M3 - Journal article
AN - SCOPUS:0025758957
VL - 25
SP - 1098
EP - 1103
JO - Environmental Science & Technology
JF - Environmental Science & Technology
SN - 0013-936X
IS - 6
ER -
ID: 228197542