The Effects of Solvent Dynamics on the Back Reaction of Solar-Thermal Energy Storage Systems
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The Effects of Solvent Dynamics on the Back Reaction of Solar-Thermal Energy Storage Systems. / Kjeldsen, Ida Lützen Hoff; Høvring, Julie Franck; Hillers-Bendtsen, Andreas Erbs; Mikkelsen, Kurt V.
I: Journal of Physical Chemistry A, Bind 127, Nr. 34, 2023, s. 7058-7069.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - The Effects of Solvent Dynamics on the Back Reaction of Solar-Thermal Energy Storage Systems
AU - Kjeldsen, Ida Lützen Hoff
AU - Høvring, Julie Franck
AU - Hillers-Bendtsen, Andreas Erbs
AU - Mikkelsen, Kurt V.
N1 - Funding Information: The authors acknowledge the Danish Council for Independent Research, DFF-0136-00081 B, and the European Union’s Horizon 2020 Framework Programme under grant agreement number 951801 for financial support. Publisher Copyright: © 2023 American Chemical Society.
PY - 2023
Y1 - 2023
N2 - We have investigated dynamic solvent effects on molecular solar-thermal energy storage systems using models describing the effects of frequency dependent viscosities and dielectric constants on chemical reaction rates. We have utilized the generalized Langevin model for understanding how the reactions are affected by the frequency dependent viscosities and dielectric constants. Our results show that the rate constants of the molecular solar-thermal energy storage systems depend strongly on the dielectric electric solvent properties and the frequency dependent viscosities of the solvents.
AB - We have investigated dynamic solvent effects on molecular solar-thermal energy storage systems using models describing the effects of frequency dependent viscosities and dielectric constants on chemical reaction rates. We have utilized the generalized Langevin model for understanding how the reactions are affected by the frequency dependent viscosities and dielectric constants. Our results show that the rate constants of the molecular solar-thermal energy storage systems depend strongly on the dielectric electric solvent properties and the frequency dependent viscosities of the solvents.
U2 - 10.1021/acs.jpca.3c02294
DO - 10.1021/acs.jpca.3c02294
M3 - Journal article
C2 - 37607346
AN - SCOPUS:85169293913
VL - 127
SP - 7058
EP - 7069
JO - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
JF - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
SN - 1089-5639
IS - 34
ER -
ID: 371559971