The Effects of Solvent Dynamics on the Back Reaction of Solar-Thermal Energy Storage Systems

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

We have investigated dynamic solvent effects on molecular solar-thermal energy storage systems using models describing the effects of frequency dependent viscosities and dielectric constants on chemical reaction rates. We have utilized the generalized Langevin model for understanding how the reactions are affected by the frequency dependent viscosities and dielectric constants. Our results show that the rate constants of the molecular solar-thermal energy storage systems depend strongly on the dielectric electric solvent properties and the frequency dependent viscosities of the solvents.

OriginalsprogEngelsk
TidsskriftJournal of Physical Chemistry A
Vol/bind127
Udgave nummer34
Sider (fra-til)7058-7069
Antal sider12
ISSN1089-5639
DOI
StatusUdgivet - 2023

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© 2023 American Chemical Society.

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